Effect of Hybridization on the Hardness Properties of Nanoclay/S-glass Fibre/Epoxy Hybrid Nanocomposites
Keywords:
Nanotechnology, Nanocomposite, S-glassfibre, Epoxy, Nanoclay, Hybrid composite, Hardness and SEMAbstract
: This study evaluates the effects of nanoclay and S-glass fibre loadings, both individually and in combination, on the hardness of epoxy composites. Three composite groups were fabricated: epoxy/S-glass fibre, epoxy/nanoclay, and epoxy/S-glass fibre/nanoclay hybrids. Hardness values ranged from 31 to 93 HRA for epoxy/S-glass fibre composites, 31 to 109.6 HRA for epoxy/nanoclay composites, and 31 to 121.8 HRA for hybrid composites. The hybrid system with 36 wt% S-glass fibre, 4 wt% nanoclay, and 60 wt% epoxy exhibited the highest hardness (121.8 HRA), representing a 78% increase over neat epoxy and 31% and 13% improvements compared to the best epoxy/S-glass fibre (93 HRA) and epoxy/nanoclay (109.6 HRA) composites, respectively. Rockwell hardness testing confirmed progressive improvement with increasing filler content, while scanning electron microscopy (SEM) revealed uniform filler dispersion at optimal loading and interfacial defects at higher concentrations. The results demonstrate that hybridization of S-glass fibre and nanoclay provides synergistic reinforcement, achieving superior hardness compared to single-filler composites. However, beyond the saturation point, excessive filler addition resulted in diminished hardness due to agglomeration and weak matrix–reinforcement interfaces.